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She appeared in her first nude photo shoot in 2001, three days after she turned 18. Lilly Ann has appeared in pornographic magazines and videos, and on pornographic websites.
Early in her pornographic career, Lilly Ann performed in hardcore pornography. Later, she performed predominantly in solo (i.e. masturbation) and lesbian scenes. Lilly Ann was Penthouse Pet of the Month in March 2003.
Lilly Ann has appeared in pornographic magazines such as Hustler, Barely Legal, and Club (magazine).
She has a tattoo of a female demon on her back, near her left shoulder.