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Though Spelvin is known to have appeared in a few sexploitation features during the late-1960s, she became one of the best-known figures in hardcore pornography for her starring role in The Devil in Miss Jones in 1973. Spelvin went on to appear in over 70 adult films, before retiring from them in 1982.
Georgina Spelvin epitomized the era of porn chic. In 1973, Robert Berkvist, writing in The New York Times, commented that "'Miss Jones' is as familiar in [the respectable and well-to-do New York suburb of] Scarsdale as she is on Broadway."