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Born in Brooklyn, New York City, Luvana's family moved to Puerto Rico when she was 5. She moved to Miami, Florida at the age of 18, and got her start as a dancer in South Beach Miami strip clubs. Luvana entered the porn industry in 2001. Her first hardcore appearance was in More Dirty Debutantes #211. She was initially a contract girl with Digital Sin/New Sensations.
Luvana did not do anal sex on camera initially, saying that she would not do anything she was not comfortable with. After doing it in her private life and finding that she liked it, she proceeded to do it on film. Her first film with an anal scene was The Perfect Secretary. She followed up by doing an anal scene in O: the Power of Submission. Since then, she has made other films without anal scenes, so it is unclear what her plans are. On June 15, 2006, Carmen won the Howard Stern Pornstar Beauty Pageant, beating Taylor Wane and Taryn Thomas for the crown. In December 2007, Luvana announced that 2008 would be her last year performing in adult films, saying that after six years in the industry "I do not want to be known [as] the girl [fans] are tired of seeing and that has been in the industry way too long."