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Her entry into pornographic films was influenced by her association with Bill Margold, with whom she shared an apartment in the mid 1980s. Margold suggested that she enter a Miss Nude contest, which she did, and won. Soon after, Alexandre entered the pornographic film industry. Alexandre has suggested that she began performing in pornography to annoy her then ex-boyfriend, who had introduced her to Margold during their relationship, in an effort to convince her to perform in pornography.
In 1991, Alexandre directed, produced, wrote, and starred in Cheeks 5: Cop A Feel. Alexandre is widely regarded as the first woman to have done this in the adult video industry. This video received a nomination for the AVN Award for Best Director. Alexandre also directed, produced, and wrote the 1992 video Best Butt(e) in the West, her last adult film performance. Other industry nominations include Best Sex Scene for the video Making Tracks (1991), and Best Supporting Actress for the video Mystic Pieces (1989).
Alexandre left the adult industry in 1992. Her most recent pornographic work continued to be released into 1993.