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She had already shot "300 or 400" scenes by the time Hollander formally started in the industry. Her first scene was in the film More Dirty Debutantes 268 with Ed Powers. As of mid-2006, she has appeared in over 125 productions, and is credited as co-director for the "Otto and Audrey Destroy the World" series of films. She won the AVN Awards Female Performer of the Year in 2006. Hollander and Bauer created their own extreme porn production called "Supercore" distributed by Mach2 Entertainment. She made her directorial debut on a Mach2 movie called pASSionate LOVE. She stated in a July 2007 interview that she has never done a scene that did not involve anal sex; furthermore, "in the past year every anal scene that I've done, I've done double anal."
She has described herself as bisexual, stating that her first same-sex encounter was when she attended cheerleader camp.