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She attended a junior college in San Diego majoring in biochemistry, while waitressing and tutoring in science and mathematics on the side, when she decided to enter modeling. She started answering newspaper ads in October, 1999, and soon began appearing on various amateur pornography websites such as Amateur Pink, Busty Amateurs, Seductive Amateurs, Darker Pleasures and BubbleGirls. In 2000, Aimee Sweet introduced Giovanni to glamour photographer Suze Randall, who in late May of that year shot photos of Giovanni which appeared in the September issue of Penthouse magazine.
Giovanni has appeared in bondage, fetish, amateur, glamour and artistic photography. Giovanni has worked extensively with Andrew Blake, appearing in Girlfriends, Aria, Blondes & Brunettes, Justine, Adriana and Naked Diva. She has appeared in softcore pornographic movies, although most of her lesbian scenes involve purely implied sexual contact. In the early part of her modeling career she made extensive use of sex toys in masturbation videos, which she has since stopped doing. In October 2008, Giovanni appeared in the first episode of James Gunn's short-form web video series, PG Porn playing a role opposite Nathan Fillion