Monroe started working as a hostess in a Hooters restaurant at age 16. While working for Hooters she posed for their calendar. Upon turning 18, she began doing nude modelling; in April 2005 she began performing in adult films.
In May of 2005 she posed for a Hustler magazine layout; two months later she learned she would be the cover model for the December issue of the magazine. In November 2005 she was signed to an exclusive contract by Hustler, becoming their second girl ever after Jessica Jaymes. In December 2006 her contract with them was renewed, but by August 2007 she had left them. She later said it was a mutual parting, as she wanted to work as an independent and Hustler wanted to focus more on their casino and the clothing line.
On June 4th 2008 she appeared on an episode of the Howard Stern show where she participated on a game show where she and 2 other porn stars took on 3 whack packers to show their intelligence.
Monroe met her future husband as a one-night stand, but they kept seeing each other afterwards. They were married in September 2006.
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